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000 nam
001 2210080240576
005 20140806142544
008 950309s1993 bnka m FB 000a kor
040 a221008
100 a옥현리
245 00 a2-Methyl pyridine 誘導體를 이용한 실라에텐(Me2Si=CH2)의 合成/d玉賢利 著. -
260 a부산:b동아대학교,c1993. -
300 a52장.:b삽도;c27cm. -
502 a학위논문(석사)-b동아대학교 대학원c화학과d94년2월
520 b영문초록 : Some 2-methyl pyridine analogue containing organosilicon groups was prepared from the reaction of 2-methyl pyridine with lithium organyl at -78℃ in the presence of Me_(3)SiCl. In case of lithiation of 2-methyl pyridine derivatives, the application of directed ortho metallation (DoM) methods with lithium organyl in α-picoline and 2,3-, 2,4-, 2,5-, 2,6-lutidine, collidine was successful in pentane solution. The structures of prepared compounds were identified by ^(1)H- and ^(13)C-NMR. The precise analysis of the ^(1)H-NMR hyperfine structures of synthetic compounds was preformed by computer simulation based on the density metrix method.
650 a실라에텐
856 adonga.dcollection.netuhttp://donga.dcollection.net/jsp/common/DcLoOrgPer.jsp?sItemId=000002141622
950 aFB
950 a비매품b₩3,000c(추정가)
2-Methyl pyridine 誘導體를 이용한 실라에텐(Me2Si=CH2)의 合成
Material type
학위논문 동서
Title
2-Methyl pyridine 誘導體를 이용한 실라에텐(Me2Si=CH2)의 合成
Author's Name
Publication
부산: 동아대학교 1993. -
Physical Description
52장: 삽도; 27cm. -
학위논문주기
학위논문(석사)- 동아대학교 대학원 화학과 94년2월
Keyword
영문초록 : Some 2-methyl pyridine analogue containing organosilicon groups was prepared from the reaction of 2-methyl pyridine with lithium organyl at -78℃ in the presence of Me_(3)SiCl. In case of lithiation of 2-methyl pyridine derivatives, the application of directed ortho metallation (DoM) methods with lithium organyl in α-picoline and 2,3-, 2,4-, 2,5-, 2,6-lutidine, collidine was successful in pentane solution. The structures of prepared compounds were identified by ^(1)H- and ^(13)C-NMR. The precise analysis of the ^(1)H-NMR hyperfine structures of synthetic compounds was preformed by computer simulation based on the density metrix method.
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IInter-Campus Loan
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