In this paper, a Mach–Zehnder interferometer temperature sensor with a single-mode fiber–thin-core fiber–single-mode fiber cascaded is designed. When the light is transmitted from the single-mode fiber to the thin-core fiber, different modes will be excited because of the mode-field mismatch. Optical power from the input fiber can be partly coupled to the cladding modes of the thin-core fiber, and the cladding modes of the thin-core fiber then re-coupled to the lead-out fiber, which constitutes the Mach–Zehnder interferometer in the output single-mode fiber. To improve the temperature sensitivity of the sensor, we coated the thermal-sensitive material (such as polymethoxane or ultraviolet glue) on the surface of the thin-core fiber. The experimental results show that the temperature sensitivity of the sensor coated with a polydimethylsiloxane film was increased from 32.0 to 90.0 pm/°C, about three times, compared to the uncoated thin-core fiber sensor. When the surface of the thin-core fiber is coated with an ultraviolet glue film, the temperature sensitivity of the sensor was increased from 32.0 to 166.8 pm/°C, about six times. The designed sensor, with compact structure, simple production, strong robustness, and high sensitivity, has a wide application prospect in industrial production and national defense technology. [ABSTRACT FROM AUTHOR]