KLi3Fe(C2O4)3: a perovskite-like compound with 1 : 3 ordering at both A and B sites.
- Resource Type
- Article
- Authors
- Yao, Wenjiao; Guo, Yuan-Yuan; Lightfoot, Philip
- Source
- Dalton Transactions: An International Journal of Inorganic Chemistry. 10/21/2017, Vol. 46 Issue 39, p13349-13351. 3p.
- Subject
- *PEROVSKITE
*BINDING sites
*MOLECULAR structure
*POTASSIUM compounds
*CATION analysis
- Language
- ISSN
- 1477-9226
KLi3Fe(C2O4)3 adopts a perovskite-like structure with 1 : 3 ordering of (Li,Fe) on the B-site and (K,vacancy) on the A-site; there are no previous examples of this type of cation ordering in conventional perovskites. [ABSTRACT FROM AUTHOR]