This document represents the second in a series of documents in which information is summarized and integrated on the chemical mechanisms for gas generation from simulated wastes that mimic the nuclear waste in Tank 241-SY. Over the past year the reliability of the instrumentation that has been installed on Tank 101-SY has been increased dramatically. Gases composed of H{sub 2}, N{sub 2}O, N{sub 2}, and NH{sub 3} are continuously released at low levels and also periodically released from the waste stored in this tank such that the lower flammability limit of 4% H{sub 2} is sometimes exceeded. To better understand the reasons for this phenomenon and with the goal of mitigating the potential safety problem associated with the flammability, instrumentation has been installed on the tank and studies have been carried out to understand the mechanism by which these gases are generated. It is worthwhile to annually summarize this information in a single document, to integrate the information, and to highlight the remaining open questions surrounding the mechanism of gas generation. This is the goal of this document. Information on simulated wastes under thermal and radiation conditions has been collected from work performed at Argonne National Laboratory, Georgia Institute of Technology, and Pacific Northwest Laboratory; this report attempts to correlate the simulated data with that of actual tank waste. This document is lengthier than the former report because so much more information was available this year.