The colorful, unfading, and eco-friendly photonic crystal structural colors have attracted wide interest from textileresearchers. However, to minimize the interference of incoherently scattered light, the preparation of the structural colorfabric is still based on the black fabric, which seriously restricts the practical application of the structural colors in textiledyeing and finishing. This paper presented a straightforward strategy to construct structural colors on the fabrics byassembling polysulfide microspheres (PSMs) with self-absorbing light properties. The monodisperse PSMs weresuccessfully synthesized through a polycondensation process between Na2S2 and 1,2,3-trichloropropane, whose particle sizecan be controlled by adjusting the volume ratio of ethanol-water. Four different structural colors were successfully obtainedon white polyester fabric by varying the diameter of the PSMs arranged on the fabric surface in a face-centered cubicstructure. Notably, the designed structural color fabrics had a low angle dependence, which was more meaningful for thetextile color measuring and matching system.