A WO_3/TiO_2 composite film was in-situ prepared in tungstate electrolyte and characterized by Electron microscopy, X-ray diffraction, UV―Vis spectrophotometer and Photoluminescence. The oxide film consists of mixture phases of anatase and rutile, showing porous structures and metallurgical bond with substrate. With the incorporation of WO_3 into TiO_2, the optical absorption edge of TiO_2 filmwas shifted to longer wavelength slightly and the separation between electrons and holes was promoted effectively. WO_3/TiO_2 composite film with increased photo quantum efficiency will be promising in the treatment of environmental pollutants.