This study investigated the pollution status of polycyclic aromatic hydrocarbons (PAHs) such as benzopyran, which is a harmful substance, in convergence herbal pills distributed in Seoul. During 2010 ~ 2013, 31 items and 93 samples were collected from the herbal medicines vendors in Seoul, and the samples were extracted, filtered, concentrated, and then spun out with SPE (Sep-pak florisil) and concentrated again and analyzed by liquid chromatography. The results of the analysis showed that the average contents of PAHs were below 10 ㎍ / ㎏, and the PAHs were lower than those of daily life exposure, and MOEs was evaluated as safe to a negligible level. In the future, comparative fusion studies on the harmful substances of medicinal pills and food pills are needed.