In this paper, we consider a cooperative relay network consisting of a source, a destination, and multiple decode-and-forward (DF) relays in the presence of multiple eavesdroppers, which intend to tap confidential messages transmitted by both the source and the relays. We propose a so-called secrecy maximization oriented relay selection (SMORS) scheme to improve the physical-layer security of wireless communications. In the SMORS scheme, a relay with the maximal secrecy rate is selected among all the DF relays to forward the source signal. We analyze the intercept probability of the proposed SMORS scheme as well as the traditional max-min relay selection scheme. Numerical results show that the proposed SMORS scheme outperforms the conventional max-min relay selection scheme in terms of the intercept probability. Additionally, it is shown that with an increasing number of eavesdroppers, the intercept performance of wireless communications degrades, which can be well addressed using the proposed SMORS scheme through increasing the number of relays. By contrast, increasing the number of relays has little impact on the intercept probability for the conventional max-min relay selection scheme, especially when the number of relays is sufficiently high (e.g., exceeding 20 relays).