Recently, the studies using the color illumination to analyze various physiological and psychological variation are being actively investigated. Therefore, in this paper, we proposed a system to collect information through smart devices using the app development based on the color environment. However, the composition of the completed color environment of the existing studies in the visual environment was difficult. So, to supplement this problem, the color environment was configured using the smart device and the HMD(Head Mounted Display). It was configured to collect the vital signs through the EMS (Bio-Medical- System). The collection of vital signs by the proposed system was based on the physiological quantification analysis, the new markers development and analysis patterns in the color environment. Through implementing this, the proposed system expected to help in medical diagnosis and treatment as well as in developing programs for the patient rehabilitation.