In Situ Formed Tribofilms as Efficient Organic/Inorganic Hybrid Interlayers for Stabilizing Lithium Metal Anodes
- Resource Type
- article
- Authors
- Shaozhen Huang; Kecheng Long; Yuejiao Chen; Tuoya Naren; Piao Qing; Xiaobo Ji; Weifeng Wei; Zhibin Wu; Libao Chen
- Source
- Nano-Micro Letters, Vol 15, Iss 1, Pp 1-14 (2023)
- Subject
- Lithium metal anode
Organic/inorganic hybrid interlayers
High current density
Fluoropolymer grease
Local desolvation environment
Technology
- Language
- English
- ISSN
- 2311-6706
2150-5551
Highlights The robust organic/inorganic hybrid interlayer derived from in situ formed tribofilms were fabricated by using a scalable rolling method. The interlayer facilitates dendrite-free lithium metal anodes by building local de-solvation environments near the interface and inhibiting both dendrite growth and electrolytes corrosion. The symmetrical cell exhibits a remarkable lifespan of 5,600 h (1.0 mA cm-2 and 1.0 mAh cm-2) and 1,350 cycles even at a harsh condition (18.0 mA cm-2 and 3.0 mAh cm-2).