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요약정보
抗泥型聚羧酸减水剂的制备及性能研究 / Preparation and properties of anti-mud polycarboxylate superplasticizer
Resource Type
Academic Journal
Authors
汪源
;
齐冬有
;
邹德麟
;
纪宪坤
;
汪智勇
;
郝禄禄
;
杨广
;
张钰
;
刘洪印
;
WANG Yuan
;
QI Dongyou
;
ZOU Delin
;
JI Xiankun
;
WANG Zhiyong
;
HAO Lulu
;
YANG Guang
;
ZHANG Yu
;
LIU Hongyin
Source
新型建筑材料 / New Building Materials
. 50(1):41-78
Subject
聚羧酸减水剂
吸附性
抗泥性能
合成
性能
Language
Chinese
ISSN
1001-702X
Online Access
Find it @ DONGA
초록
聚羧酸减水剂(PCE)中的PEO侧链对黏土非常敏感,而骨料中难免会掺杂较多黏土,尤其是钠基膨润土.通过自由基聚合在PCE的分子结构中引入抗泥功能单体全氟辛基三乙氧基硅烷,合成一种抗泥型聚羧酸减水剂(PCE-c).通过红外光谱分析表征了PCE的分子特征;通过红外光谱、热失重分析、XRD等分析表征了PCE在黏土上的吸附能力;通过净浆、混凝土等试验,评价了PCE对混凝土性能的影响.结果表明,与市售抗泥保坍型聚羧酸减水剂相比,合成的PCE-c具有更优的保坍效果,在钠基膨润土表面的吸附量更少,对水泥具有更好的吸附性和分散性.
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