We have calculated the transition energies and probabilities of one-electron one photon and one-electron two photon transitions of middle-Z and high-Z He-like ions using the fully relativistic multiconfiguration Dirac-Hartree-Fock method with active space method. The relativistic, electron correlation, Breit and QED effects are systemically taken into account in the present work. Results showcase consistent agreement with the experimental and theoretical data, uncovering intriguing inversion phenomena in One-Electron One-Photon transitions energy, particularly in double-hole states. Theoretical spectra intensities provide valuable insights into high-energy X-ray radiation processes from double \textit{K}-hole states.