We present six epochs of optical spectropolarimetry of the Type II supernova (SN) 2023ixf ranging from $\sim$ 2 to 15 days after the explosion. Polarimetry was obtained with the Kast double spectrograph on the Shane 3 m telescope at Lick Observatory, representing the earliest such observations ever captured for an SN. We observe a high continuum polarization $p_{\text{cont}} \approx 1$ % on days +1.4 and +2.5 before dropping to 0.5 % on day +3.5, persisting at that level up to day +14.5. Remarkably, this change coincides temporally with the disappearance of highly ionized "flash" features. The decrease of the continuum polarization is accompanied by a $\sim 70^\circ$ rotation of the polarization position angle ($PA$) as seen across the continuum. The early evolution of the polarization may indicate different geometric configurations of the electron-scattering atmosphere as seen before and after the disappearance of the emission lines associated with highly-ionized species (e.g., He II, C IV, N III), which are likely produced by elevated mass loss shortly prior to the SN explosion. We interpret the rapid change of polarization and $PA$ from days +2.5 to +4.5 as the time when the SN ejecta emerge from the dense asymmetric circumstellar material (CSM). The temporal evolution of the continuum polarization and the $PA$ is consistent with an aspherical SN explosion that exhibits a distinct geometry compared to the CSM. The rapid follow-up spectropolarimetry of SN 2023ixf during the shock ionization phase reveals an exceptionally asymmetric mass-loss process leading up to the explosion.
Comment: Accepted to ApJL