Reactivity of [MCl(η3-allyl)(1,10-phenanthroline)(CO)2] (M = Mo, W) Complexes toward Enolate Anions
- Resource Type
- Authors
- M. Elena Navarro Clemente; Dolores Morales; Daniel Miguel; Julio Pérez; Lucía Riera; Victor Riera
- Source
- Organometallics. 22:4124-4128
- Subject
- Inorganic Chemistry
chemistry.chemical_compound
chemistry
Stereochemistry
Phenanthroline
Organic Chemistry
Reactivity (chemistry)
Physical and Theoretical Chemistry
Medicinal chemistry
- Language
- ISSN
- 1520-6041
0276-7333
The reactions of the complexes [MCl(η3-C3H4-R)(CO)2(phen)] (1a−c; M = Mo, W) with KCH2C(O)Ar afford the O-bound enolato complexes [M(η3-C3H4-R){OC(CH2)Ar}(CO)2(phen)] (2a−d). On the other hand, the...