This paper shows the results of spatially resolved temperature measurements of the piston surface of an optically accessible direct injection spark ignition engine during flame impingement. High-speed thermographic phosphor thermometry (TPT), using Gd3Ga5O12:Cr,Ce, and planar laser-induced fluorescence of the hydroxyl radical (OH-PLIF) were used to investigate the temperature increase and the time and position of flame impingement at the piston surface. Measurements were conducted at two operating cases and showed heating rates of up to 16,000 K/s. The OH-PLIF measurements were used to localize flame impingement and calculate conditioned statistics of the temperature profiles. The TPT coating was characterized and its influence on the temperature measurements evaluated.