Spin Trapping of Radicals from the Reactions between Donor and Acceptor Olefins. Further Evidence for the Tetramethylene Diradical Intermediate as the Initiator of Spontaneous Copolymerization
- Resource Type
- Authors
- Henry K. Hall; Peter J. Steel; Ola Persson; Anne Buyle Padias; Lennart Eberson
- Source
- Macromolecules. 33:2021-2029
- Subject
- Reaction mechanism
Polymers and Plastics
Spin trapping
Diradical
Chemistry
Radical
Organic Chemistry
Reaction intermediate
Photochemistry
Acceptor
law.invention
Inorganic Chemistry
law
Polymer chemistry
Materials Chemistry
Copolymer
Electron paramagnetic resonance
- Language
- ISSN
- 1520-5835
0024-9297
EPR spectroscopy and product isolation have been used to investigate the initiation of spontaneous copolymerizations of donor and acceptor monomers. The results establish the presence of tetramethy ...