Mono- and binuclear chloride complexes of bismuth(iii) with 2-aminopyrimidine cations depending on specific synthetic route
- Resource Type
- Authors
- Alexey N. Proshin; Denis A. Pankratov; Victor A. Tafeenko; Tatiana P. Trofimova; I. S. Glazkova; Marina A. Orlova
- Source
- Mendeleev Communications. 30:202-204
- Subject
- Reaction conditions
1h nmr spectroscopy
010405 organic chemistry
Chemistry
chemistry.chemical_element
General Chemistry
010402 general chemistry
01 natural sciences
Chloride
0104 chemical sciences
Bismuth
Crystallography
Elemental analysis
medicine
Single crystal
medicine.drug
- Language
- ISSN
- 0959-9436
Complexes of Bi iii with 2-aminopyrimidine cations with metal-to-ligand ratios of 1:3 or 2:4 (depending on reaction conditions) were synthesized and characterized by elemental analysis, 1H NMR spectroscopy, and single crystal X-ray crystallography. The possibility of conversion of the latter complex into the former one was demonstrated. The determined cytotoxicity depended on the structure of these complexes.