Banana wastes can be valorised in bioethanol due to its high content in cellulose (more than 30% of total on a dry basis) and hemicelluloses (25% of total). Large amount of these wastes is generated during the banana cultivation and harvesting stage. This study proposes the use of, beside conventional acid sulphuric, different organic acids (tartaric, oxalic and citric) during acid pretreatment step, to suppress the unwanted compounds formation and improve bioethanol production. Instead, bioethanol production generates a solid waste flow that is managed in an anaerobic digestion plant, obtaining biogas, to be converted into energy, and digestate, considered as a potential biofertiliser. Life cycle assessment methodology is used to analyse the environmental profiles of four valorisation scenarios to produce bioethanol from banana peel waste. According to the results, reported per kilogram of bioethanol, the citric acid-based scenario has the worst environmental profile due to the background processes involved in the acid production (around 55% for most impact categories). Conversely, the oxalic acid-based scenario has the best environmental profile, with a decrease of around 20% and 35%, depending on the impact category, compared to the citric acid scenario. The energy requirements production (mostly thermal energy) is the main hotspot in numerous subsystems regardless of the scenario (ranging from 30% to 50% depending on the impact category). Therefore, the use of renewable energy sources to satisfy energy requirements combined with an energy optimisation of the valorisation strategies through the reuse of some internal steams, is proposed as improvement activities This research has been partially supported by the SENSE project granted by FEDER/Spanish Ministry of Science, Innovation and Universities, Spanish National Research Agency (CTQ2016-75136-P) and by the project Enhancing diversity in Mediterranean cereal farming systems (CerealMed) funded by PRIMA Programme and FEDER/Ministry of Science and Innovation – Spanish National Research Agency (PCI2020-111978). B. Santiago thanks to the Spanish Ministry of Science, Innovation and Universities for financial support (Grant reference BES-2017-081715). The authors belong to the Galician Competitive Research Group GRC 2013-032 and to CRETUS Strategic Partnership (AGRUP2015/02). All these programmes are co-funded by Xunta de Galicia and FEDER (EU) SI