The role of polymer spacers in specific adhesion
- Resource Type
- Authors
- Carlos M. Marques; André G. Moreira
- Source
- The Journal of Chemical Physics. 120:6229-6237
- Subject
- chemistry.chemical_classification
Length scale
Materials science
Bridging (networking)
Bond density
Binding energy
Time evolution
General Physics and Astronomy
Nanotechnology
Polymer
Adhesion
chemistry
Chemical physics
Molecule
Physical and Theoretical Chemistry
- Language
- ISSN
- 1089-7690
0021-9606
We study the role of flexible spacers in specific adhesion from the point of view of polymer reaction--diffusion theory. By assuming that the interactions between complementary adhesion moieties occur on a length scale much smaller than the size of the polymer spacer, we describe in detail binding and rupture between two opposing surfaces. Predictions are given for the physical properties of interest such as the time evolution of bond density and the ranges of attraction and unbinding. We also discuss the dynamic crossover between reversible and irreversible bridging.