Recyclable Transition Metal Catalysis using Bipyridine-Functionalized SBA-15 by Co-condensation of Methallylsilane with TEOS.
- Resource Type
- Academic Journal
- Authors
- Han YR; Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 03722, Republic of Korea.; Kim JS; Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 03722, Republic of Korea.; Park WJ; Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 03722, Republic of Korea.; Department of Chemistry Center for NanoMedicine, Institute for Basic Science (IBS), Seoul, 03722, Republic of Korea.; Lee CH; Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 03722, Republic of Korea.; Department of Chemistry Center for NanoMedicine, Institute for Basic Science (IBS), Seoul, 03722, Republic of Korea.; Cheon J; Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 03722, Republic of Korea.; Department of Chemistry Center for NanoMedicine, Institute for Basic Science (IBS), Seoul, 03722, Republic of Korea.; Jun CH; Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 03722, Republic of Korea.; Department of Chemistry Center for NanoMedicine, Institute for Basic Science (IBS), Seoul, 03722, Republic of Korea.
- Source
- Publisher: Wiley-VCH Country of Publication: Germany NLM ID: 101294643 Publication Model: Print-Electronic Cited Medium: Internet ISSN: 1861-471X (Electronic) Linking ISSN: 1861471X NLM ISO Abbreviation: Chem Asian J Subsets: PubMed not MEDLINE; MEDLINE
- Subject
- Language
- English
Well-defined recyclable Pd- and Rh-bipyridyl group-impregnated SBA-15 catalysts were prepared for C-C bond coupling reaction and selective hydrogenation reactions, respectively. These SBA-15 derived ligands for the catalysts were prepared by direct and indirect co-condensation method using bipyridyl-linked methallylsilane. This indirect method, involving methoxysilane generated from methallylsilane shows higher loading efficiency of transition metal catalysts on SBA-15 than the direct use of methallylsilane.
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