Guanidinium solvents with exceptional hydrogen bond donating abilities.
- Resource Type
- Academic Journal
- Authors
- Brar NK; School of Chemical Sciences, University of Auckland, Auckland, New Zealand. cameron.weber@auckland.ac.nz.; MacDiarmid Institute for Advanced Materials and Nanotechnology, Wellington, New Zealand.; Brown RT; School of Chemical Sciences, University of Auckland, Auckland, New Zealand. cameron.weber@auckland.ac.nz.; MacDiarmid Institute for Advanced Materials and Nanotechnology, Wellington, New Zealand.; Shahbaz K; Department of Chemical and Materials Engineering, University of Auckland, Auckland, New Zealand.; Hunt PA; MacDiarmid Institute for Advanced Materials and Nanotechnology, Wellington, New Zealand.; School of Chemical and Physical Sciences, Victoria University of Wellington, Wellington, New Zealand.; Weber CC; School of Chemical Sciences, University of Auckland, Auckland, New Zealand. cameron.weber@auckland.ac.nz.; MacDiarmid Institute for Advanced Materials and Nanotechnology, Wellington, New Zealand.
- Source
- Publisher: Royal Society of Chemistry Country of Publication: England NLM ID: 9610838 Publication Model: Electronic Cited Medium: Internet ISSN: 1364-548X (Electronic) Linking ISSN: 13597345 NLM ISO Abbreviation: Chem Commun (Camb) Subsets: PubMed not MEDLINE; MEDLINE
- Subject
- Language
- English
Guanidinium chloride-based solvents have been prepared using deep eutectic solvent principles. Strong hydrogen-bond (H-bond) donating abilities are established based on a range of measures of solvent polarity, including a novel 31 P NMR chemical shift method. The physical properties and origin of the strong H-bonding ability of these solvents have been explored.