Enantiopure natural deep eutectic solvents for metal–organic framework chiral induction.
- Resource Type
- Article
- Authors
- Maia, Renata A.; Fluck, Audrey; Maxim, Catalin; Louis, Benoît; Baudron, Stéphane A.
- Source
- Green Chemistry. 11/21/2023, Vol. 25 Issue 22, p9103-9108. 6p.
- Subject
- *METAL-organic frameworks
*POROUS materials
*SOLVENTS
*CIRCULAR dichroism
*EUTECTICS
*MENTHOL
*ASYMMETRIC synthesis
- Language
- ISSN
- 1463-9262
A green alternative approach to the chiral induction of a metal–organic framework (MOF) has been explored using the natural deep eutectic solvents (DES) proline : thymol (1 : 7) and menthol : thymol (1 : 1). These solvents have been successfully employed for the preparation of the MIL-103 MOF and lead to an enantioenrichment of the porous material when used in enantiopure form, as demonstrated by circular dichroism. [ABSTRACT FROM AUTHOR]