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000 nam k
001 2210080037333
005 20100222111342
007 ta
008 880110s1980 bnka m FB 000a kor
040 a221008
056 a559.724
245 00 aBi-Mo 酸化物의 ALKALI 浸出에 관하여 /d李相和 著
260 a부산:b東亞大學校 大學院,c1980
300 a26 p.:b삽도;c26 cm.
502 a학위논문(석사)--b東亞大學校 大學院:c金屬工學專攻,d1980. 2
520 b영문초록 : This study is to find out the mechanism by which reaction products form when the bismuth trioxide and molybdenum trioxide is sufficiently mixed with a mole ratio of 1 to 1 and then heated at various temperatures selected from the differntial thermal analyses. The results obtained from the experiment that these reaction products have been alkali-leached are summarised as follows; 1. The reaction products of the mixture of Bi_(2)O_(3) and MoO_(3)(mole ratio=1:1) for 500℃ are Bi_(2)MoO_(6), Bi_(4)MoO_(9) and α-Bi_(2)O_(3), whereas at above 670℃ the product obtained is identified to be Bi_(4)MoO_(9) by the reation Bi_(2)MoO_(6)+α-Bi_(2)O_(3)--- Bi_(4)MoO_(9). 2. At a temperature of 1000℃ which is above the melting point of Bi_(2)O_(3) there is not change in weight. In the temperature range of 800 ℃ to 1000℃ below the boiling point of MoO_(3), however, it is shown to be a decrease in weight by 80%. 3. The melting point of Bi_(4)MoO_(9) is found to be 950℃. The change in weight of Bi_(4)MoO_(9) formed by mixing MoO_(3) and Bi_(2)O_(3) is not shown because of the formation of the compound Bi_(4)MoO_(9). 4. The chemical reaction analysis has shown that one of the reasons why the leaching rate of roasted ores of MoS_(2) containing Bi is lowered can be explained by the fact that Bi_(2)MoO_(6) and Bi_(4)MoO_(9) are not soluble in a solution of NaOH under the condition of atomosperic pressure.
650 aBM산화물
950 aFB
950 a비매품b₩3000c(추정가)
Bi-Mo 酸化物의 ALKALI 浸出에 관하여
종류
학위논문 동서
서명
Bi-Mo 酸化物의 ALKALI 浸出에 관하여
저자명
발행사항
형태사항
26 p: 삽도; 26 cm.
학위논문주기
학위논문(석사)-- 東亞大學校 大學院: 金屬工學專攻, 1980. 2
주기사항
영문초록 : This study is to find out the mechanism by which reaction products form when the bismuth trioxide and molybdenum trioxide is sufficiently mixed with a mole ratio of 1 to 1 and then heated at various temperatures selected from the differntial thermal analyses. The results obtained from the experiment that these reaction products have been alkali-leached are summarised as follows; 1. The reaction products of the mixture of Bi_(2)O_(3) and MoO_(3)(mole ratio=1:1) for 500℃ are Bi_(2)MoO_(6), Bi_(4)MoO_(9) and α-Bi_(2)O_(3), whereas at above 670℃ the product obtained is identified to be Bi_(4)MoO_(9) by the reation Bi_(2)MoO_(6)+α-Bi_(2)O_(3)- Bi_(4)MoO_(9). 2. At a temperature of 1000℃ which is above the melting point of Bi_(2)O_(3) there is not change in weight. In the temperature range of 800 ℃ to 1000℃ below the boiling point of MoO_(3), however, it is shown to be a decrease in weight by 80%. 3. The melting point of Bi_(4)MoO_(9) is found to be 950℃. The change in weight of Bi_(4)MoO_(9) formed by mixing MoO_(3) and Bi_(2)O_(3) is not shown because of the formation of the compound Bi_(4)MoO_(9). 4. The chemical reaction analysis has shown that one of the reasons why the leaching rate of roasted ores of MoS_(2) containing Bi is lowered can be explained by the fact that Bi_(2)MoO_(6) and Bi_(4)MoO_(9) are not soluble in a solution of NaOH under the condition of atomosperic pressure.
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