주기사항
영문초록 : This study is to find out the mechanism by which reaction products form when the bismuth trioxide and molybdenum trioxide is sufficiently mixed with a mole ratio of 1 to 1 and then heated at various temperatures selected from the differntial thermal analyses. The results obtained from the experiment that these reaction products have been alkali-leached are summarised as follows; 1. The reaction products of the mixture of Bi_(2)O_(3) and MoO_(3)(mole ratio=1:1) for 500℃ are Bi_(2)MoO_(6), Bi_(4)MoO_(9) and α-Bi_(2)O_(3), whereas at above 670℃ the product obtained is identified to be Bi_(4)MoO_(9) by the reation Bi_(2)MoO_(6)+α-Bi_(2)O_(3)- Bi_(4)MoO_(9). 2. At a temperature of 1000℃ which is above the melting point of Bi_(2)O_(3) there is not change in weight. In the temperature range of 800 ℃ to 1000℃ below the boiling point of MoO_(3), however, it is shown to be a decrease in weight by 80%. 3. The melting point of Bi_(4)MoO_(9) is found to be 950℃. The change in weight of Bi_(4)MoO_(9) formed by mixing MoO_(3) and Bi_(2)O_(3) is not shown because of the formation of the compound Bi_(4)MoO_(9). 4. The chemical reaction analysis has shown that one of the reasons why the leaching rate of roasted ores of MoS_(2) containing Bi is lowered can be explained by the fact that Bi_(2)MoO_(6) and Bi_(4)MoO_(9) are not soluble in a solution of NaOH under the condition of atomosperic pressure.