Direct electrochemical reduction of dilute CO2in a flue gas eliminates the energy-consuming preprocesses of capture and condensation for preparing 100% CO2gas, and hence could decrease the total energy consumption for utilization of emitted CO2. However, it raises two major issues: (i) insufficient supply rate of CO2to the cathode electrode and (ii) preferential reduction of O2; both lower the Faradaic efficiency of the target reaction of CO2reduction. To solve these issues, we propose a new concept of gas-fed liquid-covered electrodes (GFLCEs). The reaction gas is fed to the catalyst layer across a thin liquid cover layer formed by a combination of hydrophilic and hydrophobic porous films. Owing to an extremely lower solubility of O2in an aqueous electrolyte than that of CO2, the O2concentration in the catalyst layer is sufficiently decreased while securing high CO2concentration. In the GFLCE, the catalyst is entirely immersed in the electrolyte contrasting to those of conventional gas-diffusion electrodes. Therefore, a CO2capture medium including monoethanolamine (MEA) added in the electrolyte increases the effective CO2concentration. We applied the GFLCE concept with MEA to a Ru-complex-based electrocatalyst for formate production, and achieved high Faradaic efficiencies of around 70% under direct feeding of a simulated flue gas of 15% CO2+ 4% O2+ N281% (v/v). The present concept proved here with the MEA additive is a versatile means applicable to existing electrocatalysts.