Aiming at the problem that the reliability analysis of the outdoor exposed concrete structure under the action of a single factor is not consistent with the actual service environment, a reliability analysis based on the Copula function describing multiple degradation factors is proposed. According to the actual data collected on-site, the relative quality evaluation parameters (RQEP) and relative dynamic elastic modulus evaluation parameters (RDEMEP) was selected as the key degradation indicators, and the Aperture Information Criterion (AIC) was used to determine the optimal marginal distribution function in different degradation trajectories, and obtain the most optimal edge distribution function under a single factor. Optimize the edge distributions reliability curve, establish the relationship between the edge distributions through the Copula function, and couple the edge distributions of the remaining life of the concrete to obtain the joint reliability function of the concrete under the action of the coupling factors. The results show that the selection of two degradation indicators, RQEP and RDEMEP, is helpful in establishing the concrete life prediction model in the field exposure environment, and the RDEMEP are more sensitive to the field exposure environment than the RQEP. The Gumbel Copula distribution function can reasonably predict the reliability of exposed concrete on-site under dual coupling factors. The service life of C40 and C50 exposed concrete on site is about 400 and 550 months, respectively.