Perovskite light-emitting diodes (PeLEDs) prepared by the all-solution-process are gradually coming into view due to their low cost and flexible production process. However, the performance of CsPbBr3 device is limited by the high non-radiative recombination losses due to incomplete surface coverage and grain defects. Here a quaternary ammonium salt, tetrabutylammonium hexafluorophosphate (TBA-PF6) was simultaneously introduced into perovskite emission layers (CsPbBr3) and electron transport layer (TPBi (1,3,5-Tris(1-phenyl-1Hbenzimidazol- 2-yl) benzene) dissolved in ethyl acetate). As a result, the morphology and luminescence of CsPbBr3 films were improved, and the energy level of TPBi was more conducive to charge transport. Consequently, the maximum luminance and current efficiency of the modified green-emitting PeLEDs are improved. Furthermore, the optimized device had an operating life of more than 20 min at an initial luminance of 1230 cd/ m2. This work provides a simple and easy method to be scaled up for the development of low-cost all-solutionprocessed PeLEDs.