0.2ZnAl2O4/0.8Ba0.5Sr0.5TiO3 ceramics with good dielectric temperature stability were synthesized by controlling sinteringbehavior. The relationship between sintering conditions, microstructure, and dielectric properties of ceramics was studied. Cubic structures were confirmed in all ceramics. Double sintering (DS) behavior can effectively improve the density, and thegrain size has no obvious change compared with non-repeated sintering. The maximum dielectric permittivity (220 at 10 kHz)and minimum leakage current (3.98×10-6 A/cm2 at 0.25 kV/cm) are obtained in the DS ceramics, which is superior to thoseof the single sintering ceramics. This can be ascribed to the higher relative density of the DS ceramics in contrast to the singlesintering ceramics. More importantly, the temperature stability of the DS sample in all samples is optimal due to the highsurface energy at grain boundaries and improved density. This work demonstrates a route to produce ceramics with weaktemperature sensitivity for microwave applications.