To mitigate climate change, emissions control enterprises need to innovate to strike a balance between corporate economics and the environment. Businesses are the mainstay of innovation in the marketplace, but innovation has its roots in employees, and the ability of employees to effectively implement individual innovative behavioral activities within the organization is an essential factor affecting a business's ability to innovate. Then how to promote employee's innovative behavior in emissions control enterprises? Research has shown that a positive climate for organizational innovation stimulates employee creativity, encouraging them to introduce fresh ideas and solutions to problems. Organizational commitment can increase employees' sense of belonging and identity and motivate them to contribute to the organization's growth. Psychological empowerment can increase employee autonomy and decision-making power, demonstrate creativity and initiative, and make them more willing to introduce fresh ideas and try different approaches. To promote the low-carbon development of China's emissions control enterprises and improve the innovation behavior of their employees. The study intends to provide practical policies and practical recommendations for improving employee innovation behavior, while providing some references for related industries. To this end, a total of 607 effective questionnaires were collected from emissions controls enterprises' employees in China. SPSS 26.0 and AMOS 24.0 were used for confirmation reliability analysis, exploratory factor analysis, confirmation factor analysis, path analysis and mediation effect analysis. The results show the organizational innovation climate of Chinese emission control enterprises has a positive (+) effect on employee innovation behavior; organizational commitment and psychological empowerment have a positive (+) effect on employee innovation behavior. In an organizational innovation climate, organizational commitment and psychological empowerment have a moderating effect on employee innovative behavior.