Electric vehicles have become an ultimate policy option to mitigate climate change, but there are major barriers in the scale of market diffusion. One of the key factors that lead to this is consumers' range anxiety. Several reasons cause the range anxiety such as EV range limited, charging time long and complicated, charging stations and supporting equipment insufficient,etc. Also, the low stability of EV battery is a concern for EV users. A framework of the V2V trading provides alternative EV charging infrastructures and significantly reduces range anxiety of EV users. EV users not only enjoy the convenient service of charging anytime and anywhere, but also make profits in the process of energy sharing. The proposed trading mechanism is validated using real-life EVs data of Shenzhen, one of cities with the highest EV penetration. In the future, V2V technology is promising to act as a key role in the electrification and decarbonisation of transportation.