We have investigated the step stiffness on Cu(001) surfaces as a function of step orientation by two independent methods at several temperatures near 300 K. Both sets of data agree well and show a substantial dependence of the stiffness on the angle of orientation. With the exception of steps oriented along $<110>$, the experimental stiffness is significantly larger than the stiffness calculated within the solid-on-solid (SOS) model and the Ising-model, even if next nearest-neighbor interactions are taken into account. Our results have considerable consequences for the understanding and for the theoretical modeling of equilibrium and growth phenomena, such as step meandering instabilities.
Comment: 5 pages, 2 figures