We employ a recently developed population-orbit superposition technique to simultaneously fit the stellar kinematic and age maps of 82 CALIFA spiral galaxies and obtain the ages of stars in different dynamical structures. We first evaluated the capabilities of this method on CALIFA-like mock data created from the Auriga simulations. The recovered mean ages of dynamically cold, warm, and hot components match the true values well, with an observational error of up to $20\%$ in the mock age maps. For CALIFA spiral galaxies, we find that the stellar ages of the cold, warm, and hot components all increase with the stellar mass of the galaxies, from $\overline{t_{\rm cold}}\sim2.2$ Gyr, $\overline{t_{\rm warm}}\sim2.3$ Gyr, and $\overline{t_{\rm hot}}\sim2.6$ Gyr for galaxies with stellar mass $M_*<10^{10}\,\rm M_{\odot}$, to $\overline{t_{\rm cold}}\sim4.0$ Gyr, $\overline{t_{\rm warm}}\sim5.1$ Gyr, and $\overline{t_{\rm hot}}\sim5.9$ Gyr for galaxies with $M_*>10^{11}\,\rm M_{\odot}$. About $80\%$ of the galaxies in our sample have $t_{\rm hot}>t_{\rm cold}$, and the mean values of $t_{\rm hot}-t_{\rm cold}$ also increase with stellar mass, from $0.7_{-0.2}^{+0.6}$ Gyr in low-mass galaxies ($10^{8.9}\,\rm M_{\odot}Comment: 22 pages, 18 figures