Multistep Photoisomerization of Dimesitylboron-Functionalized Stilbene Analogues
- Resource Type
- Authors
- Gang Wu; Shigehiro Yamaguchi; Naoki Ando; Yuxin Ge; Francoise Sauriol; Xiang Wang; Lijie Liu; Suning Wang
- Source
- Organic Letters. 22:3258-3262
- Subject
- Boron Compounds
Cycloaddition Reaction
Molecular Structure
Photoisomerization
010405 organic chemistry
Chemistry
Organic Chemistry
Regioselectivity
Stereoisomerism
Reaction intermediate
Photochemical Processes
010402 general chemistry
Photochemistry
01 natural sciences
Biochemistry
3. Good health
0104 chemical sciences
Stilbenes
Physical and Theoretical Chemistry
- Language
- ISSN
- 1523-7052
1523-7060
Dimesitylboron-functionalized stilbene derivatives have been found to undergo an unusual regioselective photoisomerization upon irradiation at 365 nm. Using NMR to follow the photoreaction, the structures of key reaction intermediates and the final products were established. This photoisomerization occurs in four steps