Barriers to internal rotation in CF3CFCl2, CF3CHCl2, CF3CF2Br, CF3CF2Cl, CF3CH2Br, and CF3CH2Cl: fluorine-19 and proton dynamic NMR studies; ab initio molecular orbital barrier calculations
- Resource Type
- Authors
- Leo J. Letendre; Jay H. Brown; Jacques A. Brunelle; Eugen E. Weltin; C. Hackett Bushweller
- Source
- The Journal of Physical Chemistry. 96:9225-9232
- Subject
- Trifluoromethyl
Proton
Chemistry
General Engineering
Ab initio
chemistry.chemical_element
Nuclear magnetic resonance spectroscopy
Rotation
chemistry.chemical_compound
Proton NMR
Fluorine
Physical chemistry
Molecular orbital
Physical and Theoretical Chemistry
- Language
- ISSN
- 1541-5740
0022-3654
Decoalescence of the 19 F and 1 H NMR spectra of the title compounds occurs at low temperature due to slowing trifluoromethyl rotation