Spherical CuO Nanoparticles as Catalyst for Chan–Lam Cross-Coupling Reaction under Base Free Condition
- Resource Type
- Authors
- Pangkita Deka; Sameeran Kumar Das; Monikha Chetia; Ramesh C. Deka; Utpal Bora; Pankaj Bharali
- Source
- Catalysis Letters. 148:547-554
- Subject
- 010405 organic chemistry
Chemistry
Precipitation (chemistry)
Nanoparticle
General Chemistry
010402 general chemistry
01 natural sciences
Catalysis
Coupling reaction
0104 chemical sciences
chemistry.chemical_compound
symbols.namesake
Chemical engineering
symbols
Imidazole
Raman spectroscopy
Organometallic chemistry
BET theory
- Language
- ISSN
- 1572-879X
1011-372X
An easy methodology has been developed for the N-arylation of imidazole with arylboronic acid in absence of base and ligand with the aid of as-synthesized CuO nanoparticles. The CuO nanoparticles have been synthesized via precipitation route. The as-synthesized copper oxide nanoparticles are well characterized by various analytical and spectroscopic techniques, such as powder XRD, Raman spectroscopy, TEM and BET surface area analyses. The CuO nanoparticles appear as spherical in shape with a surface area of 15.4 m2/g. The mentioned reaction successfully proceeds at moderate temperature in presence of the as-synthesized nanoparticles. The protocol is applicable to a wide variety of electronically diverse precursor moieties signifying its well applicability.