Use of kinetic isotope effects in mechanism studies. 5. Isotope effects and element effects...
- Resource Type
- Article
- Authors
- Koch, Heinz F.; Lodder, Gerrit
- Source
- Journal of the American Chemical Society. 10/22/97, Vol. 119 Issue 42, p9965. 10p. 1 Diagram, 5 Charts.
- Subject
- *ISOTOPES
- Language
- ISSN
- 0002-7863
Studies the use of kinetic isotope effects in mechanism studies. Distinction between concerted and nonconcerted alkoxide-promoted dehydrohalogenations; Comparison of the element and chlorine 35/37 isotope effects associated with ethoxide-promoted dehydrohalogenations; Attribution of lower isotope effect to the leaving group with later transition structure.