Visible‐Light‐Induced Bromination of α‐Diazo Compounds with Bromoform.
- Resource Type
- Article
- Authors
- Zhang, Xin; Lin, Junyue; Liu, Miao‐Chang; Zhou, Yun‐Bing; Wu, Hua‐Yue
- Source
- European Journal of Organic Chemistry. 1/22/2024, Vol. 27 Issue 4, p1-5. 5p.
- Subject
- *BROMOFORM
*DIAZO compounds
*VISIBLE spectra
- Language
- ISSN
- 1434-193X
An efficient visible‐light‐driven strategy for bromination of α‐diazo compounds is achieved for the construction of α‐bromoesters with bromoform. It is noteworthy that the reaction occurs under sole light irradiation without a photocatalyst or an additive. Several synthetic transformations and gram‐scale reactions demonstrate the synthetic potential of this photochemical reaction. [ABSTRACT FROM AUTHOR]