In their Research Article (e202305450), Shao-Fei Ni, Wei Tan, Feng Shi et al. describe catalytic asymmetric (4+n) cycloadditions of indolyldimethanols, leading to the construction of enantioenriched indole-fused rings. Asymmetric Organocatalysis, Chiral Phosphoric Acids, Cycloaddition, Enantioselectivity, Indoles Keywords: Asymmetric Organocatalysis; Chiral Phosphoric Acids; Cycloaddition; Enantioselectivity; Indoles EN Asymmetric Organocatalysis Chiral Phosphoric Acids Cycloaddition Enantioselectivity Indoles 1 1 1 09/06/23 20230911 NES 230911 B Developing indolyldimethanols b as four-carbon platform molecules for enantioselective cycloadditions is like climbing a higher peak of the mountain: full of challenges but exciting. [Extracted from the article]