Chiroptical induction with prism[5]arene alkoxy-homologs.
- Resource Type
- Article
- Authors
- Liang, Xiaotong; Shen, Yanling; Zhou, Dayang; Ji, Jiecheng; Wang, Hongtao; Zhao, Ting; Mori, Tadashi; Wu, Wanhua; Yang, Cheng
- Source
- Chemical Communications. 12/21/2022, Vol. 58 Issue 98, p13584-13587. 4p.
- Subject
- *AMINO acid derivatives
*BINDING constant
- Language
- ISSN
- 1359-7345
The complexation of prism[5]arenes with amino acid derivatives showed association constants of up to 107 M−1, significant CD with gabs of up to 0.8 × 10−2 and CPL with glum of 2 × 10−3. The absolute configuration-CD signal correlation was established. The CD spectra varied significantly with the substituents on the prism[5]arenes. [ABSTRACT FROM AUTHOR]