[Display omitted] • Prepared Pt-Au/P25 photo-thermal intergrade thermal-catalysis, photo-catalysis and SPR effect into synergistic catalysis and possessed highly syngas formation rate. • SPR effect induced by Pt and Au nanoparticles could effectively improve the light absorbance and response range of the catalyst, broaden the spectral response range, and break the UV region limit. • The reaction mechanism of photo-thermal dry reforming of methane was further investigated and the reaction process was further explored by in situ DRIFTS test. Driving the dry reforming of methane (DRM) reaction via integrating the photo and thermal catalysis is a promising strategy to release the greenhouse effect caused by greenhouse gases (CH 4 /CO 2). However, existing photo-thermal catalysts have limited response range to light (ultraviolet region), and broadening light response region to reaching high-performance is quite critical for DRM reaction. Here, the Pt-Au/P25 photo-thermal catalyst was proposed. The catalyst showed obvious enhancement of response range that widened to visible light region. The catalytic performance of catalyst was improved by the SPR effect. The structure–activity relationship was determined by XRD, XPS, Raman, UV–vis and PL spectra. Pt-Au/P25 catalytic performance was evaluated in different light irradiation intensity and reaction temperature. It was found that light irradiation greatly increased the catalytic performance of DRM reaction. The formation rate of H₂ was 85.38 mmol·gcat−1·h−1 and 201.92 mmol·gcat−1·h−1 for CO at 500 °C under 4.6 W·cm−2 light irradiation intensity, which were 3.09 times for H 2 and 2.08 times for CO compared with dark conditions. Moreover, The DRM reaction mechanism was investigated by in situ DRIFTS test. It was found that among the intermediate species (CH x , HCOO*, H* and so on), HCOO* was critical species for the DRM reaction to proceed. During the photo-thermal DRM reaction process, activation/dissociation of CH 4 and CO 2 and formation of H 2 steps were strengthened due to photoelectric and SPR effect by light irradiation. [ABSTRACT FROM AUTHOR]