The necessity to a priori predict the durability of high level nuclear waste (HLW) glasses on extended time scales has led to a variety of modeling approaches based primarily on solution (leachate) concentrations. The glass composition and structure control the leachate and the gel compositions which in turn control what reaction products form: the leached layer is a hydrogel and reacts with the solution (leachate) to form secondary phases some of which cause accelerated glass dissolution which is undesirable. Glasses with molar excess alkali that is not bound to glass forming (Al,Fe,B)O4 structural groups in the glass resume accelerated leaching. The hydrogels of the glasses that resume accelerated leaching at long times contain excess alkali and the leachates contain excess strong base, [SB]ex. The [SB]ex further accelerates aluminosilicate gel aging into analcime with time. Glasses with no excess molar structural alkali do not resume accelerated leaching: the glass generates weak acids, [WA], in the leachate favoring hydrogel aging into clays. These data indicate that the gel layer transforms to secondary phases in situ in response to interactions with the chemistry of a continuously evolving leachate.