Diphosphine ligand chelation and bridging and regiospecific ortho metalation in the reaction of 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) with Ir 4(CO) 12: X-ray diffraction structures of Ir 4(CO) 7(μ-CO) 3(bpcd), Ir 4(CO) 5(μ-CO) 3(bpcd)(μ-bpcd), and HIr 4(CO) 4(μ-CO) 3(bpcd)[μ-PhP(C 6H 4)C [dbnd]C(PPh 2)C(O)CH 2C(O)]