In wireless location area, the estimation precision of the TOA (the time of arrival) is low because it underutilizes the time-frequency characteristics of the OFDM signal in the OFDM system. To solve this problem, in this paper, a multipath delay estimation model based on frequency domain phase offset (FDP-MDE) is proposed. And then, a grouped joint time delay estimation algorithm (GJ-TDE) is proposed according to features of the LTE system. Simulation results show that the root mean square error (RMSE) of the GJ-TDE algorithm is 5.5034m smaller than that of the synchronization algorithm under the condition that the signal-to-noise ratio (SNR) is 0dB and the sampling interval is 8.