Hyperspectral long-wave infrared imaging (LWIR HSI) adds a promising complement to visible, near infrared, and shortwave infrared (VNIR and SWIR) HSI data in the field of mineral mapping. It enables characterization of rock-forming minerals such as silicates and carbonates, which show no detectable or extremely weak features in VNIR and SWIR In the last decades, there has been a steady increase of publications on satellite, aerial, and laboratory LWIR data. However, the application of LWIR HSI for ground-based, close-range remote sensing of vertical geological outcrops is sparsely researched and will be the focus of the current study. We present a workflow for acquisition, mosaicking, and radiometric correction of LWIR HSI data. We demonstrate the applicability of this workflow using a case study from a gravel quarry in Germany. Library spectra are used for spectral unmixing and mapping of the main lithological units, which are validated using sample X-ray diffraction (XRD) and thin section analysis as well as FTIR point spectrometer data.