An adequate sequential etching though dielectrics, silicon and permanent adhesive material was successfully developed for the damascene interconnects in the face-to-back bumpless TSV Wafer on Wafer (WOW) processes. The induced bowing taken place at the etching of permanent adhesive was optimized and no void Cu metallization was achieved. According to those TSV technology, the upper and lower stacked wafers was electrically connected without bump electrodes. The improved process such as chemical mechanical planarization (CMP) of Cu re-distribution layer (RDL) is also developed successfully to provide uniform and straight line resistance distribution and reduce the loading of TSV over-etching to avoid the interconnect open issue.