This paper demonstrates the potential use of P and L band passive measurements to determine root zone soil moisture (SM) and soil temperature (ST). SM and ST data have been taken as a function of depth during the NASA GSFC PLEX 19 experiment in the summer of 2019 at Beltsville, MD, USA. Using these data, a coherent model has been used to compute H and V brightness temperatures at frequencies of 0.8 and 1.4 GHz with an observation angle of 35 degrees. These synthetic brightness data are then used to estimate the SM and ST profiles which are represented by linear polynomials. The inversion problem is formulated as a least square problem that is solved by a global optimization method known as the Adaptive Simulated Annealing (ASA) method. Four inversion examples having different SM and ST profiles are presented. Selected results show that the standard deviation between the retrieved and measured data is less than 0.077 $\text{cm}^{3}/\text{cm}^{3}$ for SM, and 2.245 °C for ST.