{Fe6O2}-Based Assembly of a Tetradecanuclear Iron Nanocluster
- Resource Type
- article
- Authors
- Svetlana G. Baca; Paul Kögerler; Manfred Speldrich; Arkady Ellern
- Source
- Materials, Vol 4, Iss 1, Pp 300-310 (2011)
- Subject
- Iron(III) carboxylates
Solvothermal synthesis
X-ray structure
Magnetic properties
Technology
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
- Language
- English
- ISSN
- 1996-1944
The tetradecanuclear FeIII pivalate nanocluster [Fe14O10(OH)4(Piv)18], comprising a new type of metal oxide framework, has been solvothermally synthesized from a hexanuclear iron pivalate precursor in dichlormethane/acetonitrile solution. Magnetic measurements indicate the presence of very strong antiferromagnetic interactions in the cluster core.