In June 2022, Gaia DR3 has provided the astronomy community with about one million spectra from the Radial Velocity Spectrometer (RVS) covering the CaII triplet region. However, one-third of the published spectra have 15Comment: Accepted for publication in A&A. Catalog available online soon. Please contact the corresponding authors for any inquiry on the catalog or ML codes. 26 pages, 29 figures