In this paper we show that when $\mathrm{G}$ is a classical semi-simple algebraic group, $\mathrm{B}\subset\mathrm{G}$ a Borel subgroup, and $\mathrm{X} = \mathrm{G}/\mathrm{B}$, then the structure coefficients of the Belkale-Kumar product $\odot_{0}$ on $\mathrm{H}^{*}(\mathrm{X}, \mathbf{Z})$ are all either $0$ or $1$.