Time-optimal control for high-order chain-of-integrators systems with full state constraints remains an open and challenging problem in the optimal control theory domain. The behaviors of optimal control in high-order problems lack precision characterization, even where the existence of the chattering phenomenon remains unknown and overlooked. This paper establishes a theoretical framework for chattering phenomena in the considered problem, providing novel findings on the uniqueness of state constraints inducing chattering, the upper bound on switching times in an unconstrained arc during chattering, and the convergence of states and costates to the chattering limit point. For the first time, this paper proves the existence of the chattering phenomenon in the considered problem. The chattering optimal control for 4th order problems with velocity constraints is precisely solved, providing an approach to plan strictly time-optimal snap-limited trajectories. Other cases of order $n\leq4$ are proved not to allow chattering. The conclusions correct the longstanding misconception in the industry regarding the time-optimality of S-shaped trajectories with minimal switching times.