Efficient optical resolution of water-soluble self-assembled tetrahedral M4L6 cages with 1,1′-bi-2-naphthol
- Resource Type
- Authors
- Shigang Wan; Li-Li Zeng; Li-Rong Lin; Yiji Lin; Hui Zhang
- Source
- Chem. Commun.. 50:15301-15304
- Subject
- Chemistry
1,1'-Bi-2-naphthol
Resolution (electron density)
Metals and Alloys
General Chemistry
Catalysis
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Self assembled
chemistry.chemical_compound
Crystallography
Water soluble
Materials Chemistry
Ceramics and Composites
Tetrahedron
Enantiomer
Enantiomeric excess
- Language
- ISSN
- 1364-548X
1359-7345
In this paper, a water-soluble racemic self-assembled tetrahedral cage [Fe4L6](4-) was successfully resolved into their ΔΔΔΔ and ΛΛΛΛ enantiomers by (R)-/(S)-1,1'-bi-2-naphthol. The enantiomeric excess of the resolved Fe(II) cage was 99%.